6,7-Diphenyl-5-thia-7-azaspiro[2.6]nonan-8-one

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6,7-Diphenyl-5-thia-7-aza­spiro­[2.6]nonan-8-one

The asymmetric unit of the title compound, C19H19NOS, contains two independent mol-ecules (A and B), in both of which the 1,3-thia-zepan-4-one ring adopts a chair-type conformation. The dihedral angles between the two phenyl rings are 65.28 (8) and 60.31 (9)° for mol-ecules A and B, respectively. In the crystal, mol-ecules are linked by weak C-H⋯O inter-actions, resulting in a three-dimensional...

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In the title compound, C(14)H(14)N(2)O(5)S(2)·H(2)O, the six-membered ring fused to the β-lactam unit has a twisted conformation. Weak intra-molecular N-H⋯S and C-H⋯O inter-actions occur. Inter-molecular C-H⋯S, N-H⋯O, C-H⋯O and O-H⋯O hydrogen-bonding inter-actions stabilize the crystal structure, forming a three-dimensional network. Weak C-H⋯π inter-actions are also present.

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Cholest-5-en-7-one

In the deca-hydro-phenanthrenone ring system of the title compound, C(27)H(44)O, the two cyclo-hexane rings adopt chair conformations, whereas the cyclo-hexene ring adopts an envelope conformation. The cyclo-pentane ring is twisted. In the crystal structure, mol-ecules are stacked along the a axis, but no significant inter-molecular inter-actions are observed.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813027979